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Reaction intermediates in the selective reduction of NO with propene over Ga2O3-Al2O3 and In2O3-Al2O3 catalysts

Identifieur interne : 010A54 ( Main/Repository ); précédent : 010A53; suivant : 010A55

Reaction intermediates in the selective reduction of NO with propene over Ga2O3-Al2O3 and In2O3-Al2O3 catalysts

Auteurs : RBID : Pascal:02-0047851

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English descriptors

Abstract

Minor products formed in the reaction of NO + C3H6 + O2 over Ga2O3-Al2O3 and In2O3-Al2O3 were identified by using GC-MS technique. A lot of minor products, such as oxygenated, nitrile, nitrite compounds and higher hydrocarbons were detected on both catalysts. The formation of surface nitrile species in the NO + C3H6 + O2 reaction was also recognized in the diffuse reflectance FT-IR spectra. FT-IR spectra showed that the reaction starts with the formation of adsorbed nitrate (NO3-) species via NO oxidation by O2. From the comparison of the distribution of minor products in NO + C3H6 + O2 and 2-nitropropane oxidation, a reaction pathway in which NO reduction proceeds through the formation of organic nitro compounds and subsequent decomposition to some oxygenated and nitrile compounds was proposed.

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Pascal:02-0047851

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<title xml:lang="en" level="a">Reaction intermediates in the selective reduction of NO with propene over Ga
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
and In
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
catalysts</title>
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<name sortKey="Haneda, Masaaki" uniqKey="Haneda M">Masaaki Haneda</name>
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<name sortKey="Menezo, Jean Christophe" uniqKey="Menezo J">Jean-Christophe Menezo</name>
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<name sortKey="Duprez, Daniel" uniqKey="Duprez D">Daniel Duprez</name>
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<name sortKey="Barbier, Jacques" uniqKey="Barbier J">Jacques Barbier</name>
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<name sortKey="Bion, Nicolas" uniqKey="Bion N">Nicolas Bion</name>
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<name sortKey="Daturi, Marco" uniqKey="Daturi M">Marco Daturi</name>
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<name sortKey="Lavalley, Jean Claude" uniqKey="Lavalley J">Jean-Claude Lavalley</name>
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<author>
<name sortKey="Hamada, Hideaki" uniqKey="Hamada H">Hideaki Hamada</name>
<affiliation wicri:level="1">
<inist:fA14 i1="03">
<s1>National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 5, 1-1-1 Higashi</s1>
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<idno type="inist">02-0047851</idno>
<date when="2001">2001</date>
<idno type="stanalyst">PASCAL 02-0047851 INIST</idno>
<idno type="RBID">Pascal:02-0047851</idno>
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<idno type="ISSN">1381-1169</idno>
<title level="j" type="abbreviated">J. mol. catal., A Chem.</title>
<title level="j" type="main">Journal of molecular catalysis. A, Chemical</title>
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<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Alkene</term>
<term>Alumina</term>
<term>Binary compound</term>
<term>Chemical reduction</term>
<term>Gallium Oxides</term>
<term>Heterogeneous catalysis</term>
<term>Hydrocarbon</term>
<term>Indium Oxides</term>
<term>Infrared spectrometry</term>
<term>Mixed catalyst</term>
<term>Nitric oxide</term>
<term>Oxygen</term>
<term>Propene</term>
<term>Reaction intermediate</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Intermédiaire réaction</term>
<term>Réduction chimique</term>
<term>Propène</term>
<term>Catalyseur mixte</term>
<term>Azote monoxyde</term>
<term>Gallium Oxyde</term>
<term>Alumine</term>
<term>Indium Oxyde</term>
<term>Composé binaire</term>
<term>Oxygène</term>
<term>Hydrocarbure</term>
<term>Alcène</term>
<term>Spectrométrie IR</term>
<term>Catalyse hétérogène</term>
<term>Ga2O3</term>
<term>Ga O</term>
<term>Al2O3</term>
<term>Al O</term>
<term>In2O3</term>
<term>In O</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr">
<term>Oxygène</term>
<term>Hydrocarbure</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">Minor products formed in the reaction of NO + C
<sub>3</sub>
H
<sub>6</sub>
+ O
<sub>2</sub>
over Ga
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
and In
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
were identified by using GC-MS technique. A lot of minor products, such as oxygenated, nitrile, nitrite compounds and higher hydrocarbons were detected on both catalysts. The formation of surface nitrile species in the NO + C
<sub>3</sub>
H
<sub>6</sub>
+ O
<sub>2</sub>
reaction was also recognized in the diffuse reflectance FT-IR spectra. FT-IR spectra showed that the reaction starts with the formation of adsorbed nitrate (NO
<sub>3</sub>
<sup>-</sup>
) species via NO oxidation by O
<sub>2</sub>
. From the comparison of the distribution of minor products in NO + C
<sub>3</sub>
H
<sub>6</sub>
+ O
<sub>2</sub>
and 2-nitropropane oxidation, a reaction pathway in which NO reduction proceeds through the formation of organic nitro compounds and subsequent decomposition to some oxygenated and nitrile compounds was proposed.</div>
</front>
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<s1>Reaction intermediates in the selective reduction of NO with propene over Ga
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
and In
<sub>2</sub>
O
<sub>3</sub>
-Al
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O
<sub>3</sub>
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<s0>Minor products formed in the reaction of NO + C
<sub>3</sub>
H
<sub>6</sub>
+ O
<sub>2</sub>
over Ga
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
and In
<sub>2</sub>
O
<sub>3</sub>
-Al
<sub>2</sub>
O
<sub>3</sub>
were identified by using GC-MS technique. A lot of minor products, such as oxygenated, nitrile, nitrite compounds and higher hydrocarbons were detected on both catalysts. The formation of surface nitrile species in the NO + C
<sub>3</sub>
H
<sub>6</sub>
+ O
<sub>2</sub>
reaction was also recognized in the diffuse reflectance FT-IR spectra. FT-IR spectra showed that the reaction starts with the formation of adsorbed nitrate (NO
<sub>3</sub>
<sup>-</sup>
) species via NO oxidation by O
<sub>2</sub>
. From the comparison of the distribution of minor products in NO + C
<sub>3</sub>
H
<sub>6</sub>
+ O
<sub>2</sub>
and 2-nitropropane oxidation, a reaction pathway in which NO reduction proceeds through the formation of organic nitro compounds and subsequent decomposition to some oxygenated and nitrile compounds was proposed.</s0>
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<fC02 i1="01" i2="X">
<s0>001C01A03B</s0>
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<s5>01</s5>
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<s5>01</s5>
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<s5>01</s5>
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<s5>03</s5>
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<s5>03</s5>
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<fC03 i1="03" i2="X" l="FRE">
<s0>Propène</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Propene</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Propeno</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Catalyseur mixte</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Mixed catalyst</s0>
<s5>05</s5>
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<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Azote monoxyde</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s2>FX</s2>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Nitric oxide</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s2>FX</s2>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Nitrógeno monóxido</s0>
<s1>ENT</s1>
<s2>NK</s2>
<s2>FX</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Gallium Oxyde</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Gallium Oxides</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Galio Óxido</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Alumine</s0>
<s1>ACT</s1>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Alumina</s0>
<s1>ACT</s1>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Alúmina</s0>
<s1>ACT</s1>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Indium Oxyde</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Indium Oxides</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Indio Óxido</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Composé binaire</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Binary compound</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Compuesto binario</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Oxygène</s0>
<s1>ENT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Oxygen</s0>
<s1>ENT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Oxígeno</s0>
<s1>ENT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Hydrocarbure</s0>
<s2>FX</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Hydrocarbon</s0>
<s2>FX</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Hidrocarburo</s0>
<s2>FX</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Alcène</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Alkene</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Alqueno</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Spectrométrie IR</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Infrared spectrometry</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Espectrometría IR</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Catalyse hétérogène</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Heterogeneous catalysis</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Catálisis heterogénea</s0>
<s5>17</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Ga2O3</s0>
<s4>INC</s4>
<s5>32</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Ga O</s0>
<s4>INC</s4>
<s5>33</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Al2O3</s0>
<s4>INC</s4>
<s5>34</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Al O</s0>
<s4>INC</s4>
<s5>35</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>In2O3</s0>
<s4>INC</s4>
<s5>36</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>In O</s0>
<s4>INC</s4>
<s5>37</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Métal groupe IIIB Composé</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>14</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Group IIIB metal Compounds</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>14</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Metal grupo IIIB Compuesto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>14</s5>
</fC07>
<fN21>
<s1>021</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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